Anodic Reaction of Pyrite and Galena in Acidic Solution

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Pyrite dissolution in acidic media

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Comment on ‘‘Pyrite dissolution in acidic media’’ by M. Descostes,

In a recent paper, Descostes et al. (2004) present data on a series of pyrite oxidation batch experiments conducted near pH 2 and 3 where they demonstrate very well the non-stoichiometric dissolution/oxidation of pyrite in acidic solutions through an extensive laboratory investigation of S/Fe ratios. The authors utilized this data to propose a ‘mechanism’ of pyrite oxidation based on these data...

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At an initial pH of 2, while abiotic oxidation of aqueous Fe(2+) was enhanced by a flux of H2O2 at micromolar concentrations, bio-oxidation of aqueous Fe(2+) could be impeded due to oxidative stress/damage in Acidithiobacillus ferrooxidans caused by Fenton reaction-derived hydroxyl radical, particularly when the molar ratio of Fe(2+) to H2O2 was low. When pyrite cubes were intermittently expose...

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ژورنال

عنوان ژورنال: Journal of the Japan Institute of Metals and Materials

سال: 1973

ISSN: 0021-4876,1880-6880

DOI: 10.2320/jinstmet1952.37.5_529